By default we have Exchange 2013 installed and are not automatically discovered when the client configures Outlook. will always prompt for the user name and password, entered after the completion of the normal login.
Because Exchange 2013 Autodiscover is dependent on the Autodiscover SRV records in Autodiscover and DNS in IIS. After you install Exchange 2013, IIS automatically generates
Autodiscover, but the SRV records in DNS need to be added manually.
For more information on how Autodiscover works, please refer to the following link
1, https://technet.microsoft.com/zh-cn/library/bb124251.aspx
2, http://www.exchangecn.com/exchange2007/20141130_525.html
Autodiscover settings details are as follows,
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Once set up, our clients can automatically discover and configure Outlook, such as
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Exchange 2013 clients cannot automatically discover