The company set up a network access restriction rule for a wired network, how do I break a program to use a wireless network?

The general corporate network will be divided into the intranet (wired) and the external network (wireless), and the network access restrictions rules, resulting in some applications can not be used, this situation we want to be connected to the intranet, but also hope that some programs can access the extranet. What do we do? The following configuration can be used to solve this requirement:

First connect to a wireless network that has access to the extranet, and then turn on the network properties to tick the red circle and configure my cool dog to have access to the extranet. Ah haha haha.

The company set up a network access restriction rule for a wired network, how do I break a program to use a wireless network?