Titanium (IV) chloride

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Structural Type physical and chemical properties
I want to supply I want to buy four titanium tetrachloride English name Titanium (IV) chloride
cas number 7550-45-0 molecular weight 189. 67900
density 1.726 boiling point 135-136ºc
molecular formula Cl4ti melting point -25ºc
Product use
"Use one"
For the preparation of sponge titanium and titanium dioxide, and used as a catalyst, etc.
"Use two"
Used as an analytical reagent and as raw material and smoke agent for preparation of titanium trichloride and titanium
"Use three"
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name
[Chinese name]: Titanium (IV) chloride
[English name]: Titanium (IV) chloride
[English aliases]: Titanium (IV) chloride | Titanium chloride
[English aliases]: Titanium tetrachloride
physical and chemical properties
[density]: 1.726
[boiling point]: 135-136ºc
[melting Point]: -25ºc
[Molecular formula]: cl4ti
[Molecular weight]: 189.67900
[Flash Point]: 8ºc
[precision Mass]: 187.82300
[Logp]: 2.75800
[appearance traits]: transparent light yellow liquid
[Refractive index]: 1.61
[storage conditions]: The warehouse is ventilated at low temperature and is stored separately from alkali, oxidizing agent, organic matter and flammable material
MSDS
GB Number: 81051
CAS: 7550-45-0
Chinese name: Titanium (IV) chloride
English Name: Titanium Tetrachloride;titanic chloride
Alias Titanium chloride
Molecular formula: TiCl4
Molecular Weight: 189.71
Melting Point -25℃ boiling point: 136.4 ℃
Density Relative density (water =1) 1.73
Steam Pressure:
Solubility of: Soluble in cold water, ethanol, dilute hydrochloric acid
Stability: Stability
Appearance and character: Colorless or yellowish liquid with a pungent sour taste. Smoke in the air
Hazard marking: 20 (acidic corrosive products)
Use Used in the manufacture of titanium salts, iridescent agents, artificial pearls, smoke screens, pigments, fabric mordant, etc.

2. Impact on the environment:
First, health hazards

Invasive pathway: inhalation, ingestion.
Health hazard: Direct contact with liquid titanium tetrachloride can cause different degrees of burns. Its smoke has a strong stimulating effect on the mucous membranes of the respiratory tract. Mild poisoning has wheezing bronchitis, severe respiratory difficulties, respiratory pulse, increased temperature, cough, etc., can develop into pulmonary edema.

Ii. toxicological information and environmental behavior

Toxicity: High toxicity category.
Acute toxicity: lc50400mg/m3 (rat inhalation)

Hazardous properties: Heat or water liberation, release toxic corrosive fumes.
Combustion (decomposition) Products: chloride, titanium oxide.

3. On-Site emergency monitoring methods:


4. Laboratory Monitoring methods:
Titration method (EPA Method 9252)
Gas chromatography, reference to the Handbook of Analytical Chemistry (fourth fascicle, chromatography), Chemical industry Press

5. Environmental standards:
The highest allowable concentration of hazardous substances in the air of the former Soviet Union 1mg/m3

6. Emergency treatment and disposal methods:
First, leakage emergency treatment

Evacuate the contaminated area personnel to the safe zone, prohibit unrelated personnel into the contaminated areas, recommended emergency treatment personnel wearing positive pressure self-contained breathing apparatus, wear chemical protective clothing. Do not contact the leak directly, in order to ensure the safety of the leak. Water mist slows evaporation (or diffusion), but does not spray directly on leaks or leaking points. Sprinkle the ground with soda ash, then rinse with plenty of water, and dilute the wash into the waste water system. If a large number of leaks, preferably without water treatment, under the guidance of technicians to clear.

Second, protective measures

Respiratory protection: You should wear an anti-virus mask when you may be exposed to steam. Wear gas masks when necessary.
Eye Protection: Wear chemical safety goggles.
Protective clothing: Wear overalls (anti-corrosion material production).
Hand Protection: wear rubber gloves.
Other: After work, shower dressing. Store contaminated clothes separately and use them after washing. Keep a good hygiene habit.

Third, first aid measures

Skin Contact: Wipe off poison with soft paper or cotton as soon as possible, then rinse thoroughly with water. If there is burns, seek medical treatment.
Eye contact: Immediately lift eyelid, rinse with flowing water for 10 minutes or rinse with 2% sodium bicarbonate solution. Medical treatment.
Inhalation: Rapid departure from the scene to fresh air. Keep respiratory tract unobstructed. Give oxygen when you have difficulty breathing. Give 2-4% sodium bicarbonate solution atomized inhalation. Medical treatment.
Ingestion: Rinse immediately when the patient is awake and give milk or egg whites. Seek medical attention immediately.

Fire extinguishing method: dry powder, sand. Water is forbidden.
Toxicity
CHEMICAL identification
RTECS Number:
XR1925000
CHEMICAL NAME:
Titanium chloride (TiCl4)
CAS REGISTRY Number:
7550-45-0
Last UPDATED:
199710
DATA ITEMS Cited:
7
MOLECULAR FORMULA:
Cl4-ti
MOLECULAR WEIGHT:
189.70
Wiswesser Line NOTATION:
TI G4
Health HAZARD Dataacute Toxicity DATA
TYPE of TEST:
Lc50-lethal concentration, percent kill
ROUTE of EXPOSURE:
inhalation
Species observed:
Rodent-rat
Dose/duration:
mg/m3
TOXIC EFFECTS:
Details of toxic effects not reported other than lethal dose value
REFERENCE:
85GMAT "Toxicometric Parameters of Industrial Toxic Chemicals under single Exposure," Izmerov, N.f., et al., Moscow , Centre of International Projects, GKNT, 1982 Volume (issue)/page/year:-,111,1982
TYPE of TEST:
Lc50-lethal concentration, percent kill
ROUTE of EXPOSURE:
inhalation
Species observed:
Rodent-mouse
Dose/duration:
mg/m3/2h
TOXIC EFFECTS:
Details of toxic effects not reported other than lethal dose value
REFERENCE:
85GMAT "Toxicometric Parameters of Industrial Toxic Chemicals under single Exposure," Izmerov, N.f., et al., Moscow , Centre of International Projects, GKNT, 1982 Volume (issue)/page/year:-,111,1982 * Other multiple DOSE toxicity DATA * *
TYPE of TEST:
Tclo-lowest published toxic concentration
ROUTE of EXPOSURE:
inhalation
Species observed:
Rodent-rat
Dose/duration:
Ten mg/m3/6h/2y-i
TOXIC EFFECTS:
lungs, Thorax, or respiration-other changes lungs, Thorax, or respiration-changes in lung weight related to Ch Ronic Data-death
REFERENCE:
TXAPA9 Toxicology and Applied Pharmacology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) v.1-1959-volume (issue)/page/year:83,30,1986 * * NIOSH standards Development and Surveillan CE DATA * * * NIOSH occupational EXPOSURE SURVEY data:nohs-national occupational Hazard SURVEY (1974) Nohs Hazard Code- 84219 No. of facilities:62 (estimated) No. of Industries:3 No. of Occupations:9 No. of employees:1337 (estimated) noes-national occupational Exposure Survey (1983) Noes Hazard Code-84219 No. of facilities:81 (estimated) No. of Industries:3 No. of Occupations:5 No. of employees:2107 (estimated) No. of Female employees:131 (estimated)
Security Information
[Dangerous Goods sign]: f:flammable; c:corrosive;
[Hazard Class Code]: R11; R14; R34; R48/20; R63; R65; R67
[Safety Instructions]: S26-s36/37/39-s45-s46-s62-s7/8
[Dangerous goods Transport Code]: UN 1838/2443
[Packing class]: Ii
[Customs Code]: 2827399000
Upper and downstream products
Upstream Product 9

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Preparation"Method One"
Chlorination method will be high titanium slag and petroleum coke according to a certain proportion of the batching, crushing, through the human chlorine reaction, the formation of four titanium chloride gas, after condensation, the liquefied four titanium chloride liquid, filtration, distillation, to obtain four of titanium chloride finished products. Its
Tio2+2c+2c12→ticl4+2co↑
Tio2+c+2c12→ticl4+co2↑Customs
[Customs Code]: 2827399000

Titanium (IV) chloride

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