Recently switched to Windows 10, to decrypt a document under RMS encryption as a different identity, you want to run Office under a different identity, but even holding down the SHIFT key does not see the Run as other User menu item. Had to use a compromise method to run CMD first, and then execute the runas command. After finding the Internet, I found that there was a setting like this in Group Policy. It should be set as a whole domain-wide configuration, which would be easier for users.
To open a method:
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Effect:
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Add "Run as another user" menu in Windows 10 for Applications in the Start menu